January 1, 2012

Selective hydrogenation of higher saturated carboxylic acids to alcohols using a ReOx–Pd/SiO2 catalyst

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Abstract

Higher fatty alcohols were synthesized in high yield (>92%) by direct hydrogenation of fatty acids catalyzed by ReOx–Pd/SiO2. High catalytic performance of ReOx–Pd/SiO2 can be generated by the synergy between ReOx and Pd. Preferential adsorption of the carboxylic acid to alcohols prohibited the overreaction of alcohols to alkanes.

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Takeda et al. (Sun,) studied this question.

synapsesocial.com/papers/69ffe84d6018b8d0892d9e10 https://doi.org/https://doi.org/10.1039/c2cy20302b

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