Structure and Evolution of Quasi‐Solid‐State Hybrid Electrolytes Formed Inside Electrochemical Cells

particles and poly(DOL) lead to co-crystallization-anchoring the nanoparticles in their host It also enables polymerization-depolymerization processes in DOL to be studied and controlled. The utility of the in-situ-formed HSPE, is demonstrated first in Li|HSPE|Cu half cells, which manifest Coulombic efficiencies (CE) values approaching 99%. HSPEs are also demonstrated in solid-state lithium-sulfur-polyacrylonitrile (SPAN) composite full-cell batteries. The in-situ-formed Li|HSPE|SPAN cells show good cycling stability and thus provide a promising path toward all-solid-state batteries.