February 19, 2013

Chiral Gold Complex-Catalyzed Hetero-Diels–Alder Reaction of Diazenes: Highly Enantioselective and General for Dienes

BLBin LiuUniversity of Science and Technology of China KLKangnan LiUniversity of Science and Technology of China SLShi‐Wei LuoMinzu University of China

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Abstract

A chiral gold(I) complex-catalyzed highly regio- and enantioselective azo hetero-Diels-Alder reaction has been developed. The chiral gold(I) complex acting as a Lewis acid exhibits high efficiency in the activation of urea-based diazene dienophiles. Moreover, this chiral gold catalyst also rendered a cascade intramolecular enyne cycloisomerization/asymmetric azo-HDA reaction.

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synapsesocial.com/papers/6a01fd78e8ec6bd19dcb1422 https://doi.org/https://doi.org/10.1021/ja3110472

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