Passive thermoregulatory textiles, operating without external energy input, play a crucial role in maintaining the human body within the thermal comfort zone. However, integrating autonomous environmental adaptability with superior wearing comfort into a single textile remains a challenge. In this work, inspired by the autonomous actuation of water lilies, we proposed an intelligent strategy to fabricate thermoregulatory textiles that dynamically adapted to ambient temperature fluctuations, driven by a bidirectional shape memory polymer (SMP). To concurrently achieve robust thermal adaptability and human-body-compatible softness, a crosslinked polyethylene glycol–butyl acrylate (PEG-BA) bidirectional SMP network was engineered. The PEG phase, featuring a broad crystal size distribution, provided the dynamic skeleton for thermally induced actuation, while the incorporation of the BA component tuned the intrinsic softness to match conventional soft textiles. Consequently, the synthesized PEG-BA network exhibited an exceptional bidirectional shape memory effect with a reversible strain of 15.5%, while maintaining high macroscopic softness comparable to that of human skin. By integrating this bidirectional polymer into a garment to form adaptive vents, the smart textile demonstrated the capability to significantly elevate human thermal comfort. Specifically, the vents autonomously open in hot environments to accelerate heat dissipation and close in cool environments to suppress heat loss. Given its exceptional personal thermoregulatory performance and wearing compliance, this proposed strategy exhibits considerable potential for maintaining optimal human comfort against fluctuating environmental conditions.
Yan et al. (Fri,) studied this question.