Perturbation problems in quantum mechanics

Abstract One of the great achievements of the Schrödinger wave-mechanics is the elegance of its perturbation theory, which has brought many problems, formerly considered intractable, within the range of a highly-developed mathematical technique. It is not necessary at this stage to review the numerous applications which have been made of this perturbation theory or to dwell upon its many advantages. The important advance towards an understanding of chemical forces which it has made possible is in itself a considerable achievement. There are, however, certain disadvantages in the perturbation theory in its present form, which limit the extent of its applications to complex problems of atomic and molecular structure. If the interaction of atoms, for instance, is to be calculated, as it most desirable, improved methods will have to be found.