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The unexpected isomerization of N-ethyl 6,6-pyrrolidino-Y3N@C80 to the 5,6 regioisomer is reported, as well as the synthesis, characterization, and electrochemical analysis of Er3N@C80 derivatives. A complete electrochemical study of the M3N@C80 species (M = Sc, Y, Er) and their derivatives is presented. We introduce electrochemistry as a new tool in the characterization of the 5,6 and 6,6 regioisomers of trimetallic nitride endohedral metallofullerenes.
Cardona et al. (Fri,) studied this question.
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