Quantum discord for general two-qubit states: Analytical progress

We present a reliable algorithm to evaluate quantum discord for general two-qubit states, amending and extending an approach recently put forward for the subclass of X states. A closed expression for the discord of arbitrary states of two qubits cannot be obtained, as the optimization problem for the conditional entropy requires the solution to a pair of transcendental equations in the state parameters. We apply our algorithm to run a numerical comparison between quantum discord and an alternative, computable measure of nonclassical correlations, namely, the geometric discord. We identify the extremally nonclassically correlated two-qubit states according to the (normalized) geometric discord, at a fixed value of the conventional quantum discord. The latter cannot exceed the square root of the former for systems of two qubits.