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A refined technique is described for approximating the numerically given radial part of atomic wave functions associated with self-consistent fields with exchange by means of Slater's analytical functions obtained by replacing each exponential in a hydrogen-like wave function by the sum of one, two, three, or more exponentials. Exponents and coefficients of these exponentials are calculated for the 3p-function of Cl^-, corresponding to an accuracy of 0. 0015 for the normalized radial part, and, with slightly less accuracy, for all the functions of two closed-shell ions, F^- (without exchange) and Na^+, and for some neutral first-row atoms, C (^1D), N (^2P), and O (^1S). The interpolation problem is discussed, and a new interpolation rule for the coefficients is stated, which gives excellent agreement (0. 001) in the examples chosen, namely the 1s-functions of the He-like ions and the 2p-functions of Na^+, Mg^+2, and Si^+4.
Per‐Olov Löwdin (Wed,) studied this question.