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The tin(II) complex [HC{C(Me)NAr}2]Sn(OPri) (Ar = 2,6-Pri2C6H3) functions as an effective initiator for the living polymerization of rac-lactide to produce heterotactic-enriched poly(lactide). Novelty: ClaimNovelty.NOVEL_FINDING. Consensus alignment: ConsensusAlignment.NEUTRAL.

January 1, 2001Chemical Communications144 citations

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A well defined tin(ii) initiator for the living polymerisation of lactide

ADAndrew P. DoveUniversity of Birmingham VGV.C. GibsonImperial College London EME.L. MarshallUniversity of Leeds

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Abstract

HCC (Me) NAr2Sn (OPri) (Ar = 2, 6-Pri2C6H3) is shown to be an initiator for the living polymerisation of rac-lactide to heterotactic-enriched poly (lactide).

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A well defined tin(ii) initiator for the living polymerisation of lactide

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