November 4, 2010

Total Synthesis of (±) Maoecrystal V

JGJianxian GongPeking University GLGuang LinNorth China University of Technology WSWenbo SunCentral South University

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Abstract

A concise first total synthesis of (±) maoecrystal V (1) is reported. The synthesis features a Wessely oxidative dearomatization of a phenol, an intramolecular Diels-Alder reaction, and a Rh-catalyzed O-H bond insertion as key steps.

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Gong et al. (Thu,) studied this question.

synapsesocial.com/papers/6a6552a30f05e24a8bb2e977 https://doi.org/https://doi.org/10.1021/ja108907x

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