October 1, 2001Angewandte Chemie International Edition108 citations

A Practical and Green Chemical Process: Fluoroalkyldistannoxane-Catalyzed Biphasic Transesterification

JXJiannan XiangHunan University STShinji ToyoshimaOkayama University of Science AOAkihiro OritaOkayama University of Science

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Abstract

There is no need for the recovery of the catalyst in the fluorous biphasic transesterification catalyzed by Cl (C6F13CH2CH2) 2SnOSn (C6F13CH2CH2) 2Cl2 (1; see scheme), which results in quantitative conversions and yields. An FC-72 solution of the dimeric fluoroalkyldistannoxane 1 can be recycled repeatedly without having to recover the neat catalyst.

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Cite This Study

Xiang et al. (2001) studied this question.

synapsesocial.com/papers/6a7ce6715ea1f309fbcd8c2d https://doi.org/https://doi.org/10.1002/1521-3773(20011001)40:19<3670::aid-anie3670>3.0.co;2-9

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