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Anionic Inverse Vulcanization of 3-Methyleneazetidine for Reusable Adhesives | Synapse

February 28, 2026

Anionic Inverse Vulcanization of 3-Methyleneazetidine for Reusable Adhesives

Puntos clave

The aim is to explore the copolymerization of 3-methyleneazetidine with elemental sulfur to create new materials for reusable adhesives.
Copolymerization of 3-methyleneazetidine with sulfur
Anionic reaction pathway
Conducted at 120 °C
Produced high-sulfur-content polysulfides
Polysulfides contain amine functionalities
Developed materials suitable for adhesive applications

Resumen

In this work, 3-methyleneazetidine copolymerizes with elemental sulfur via an anionic pathway at 120 °C to afford high-sulfurcontent polysulfides bearing amine functionalities. The strained four-membered heterocycle, featuring an exocyclic methylene...

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Cite This Study

Gao et al. (Thu,) studied this question.

synapsesocial.com/papers/69a286a70a974eb0d3c01c8a https://doi.org/https://doi.org/10.1039/d6cc00167j