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February 28, 2026

Anionic Inverse Vulcanization of 3-Methyleneazetidine for Reusable Adhesives

Key Points

The aim is to explore the copolymerization of 3-methyleneazetidine with elemental sulfur to create new materials for reusable adhesives.
Copolymerization of 3-methyleneazetidine with sulfur
Anionic reaction pathway
Conducted at 120 °C
Produced high-sulfur-content polysulfides
Polysulfides contain amine functionalities
Developed materials suitable for adhesive applications

Abstract

In this work, 3-methyleneazetidine copolymerizes with elemental sulfur via an anionic pathway at 120 °C to afford high-sulfurcontent polysulfides bearing amine functionalities. The strained four-membered heterocycle, featuring an exocyclic methylene...

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Authors

P

Pinxian Gao

W

Weishu Yang

W

WeiXuan Lai

Guangdong University of Technology

Journals

Chemical Communications

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Cite this study

Gao et al. (Thu,) studied this question.

synapsesocial.com/papers/69a286a70a974eb0d3c01c8a — DOI: https://doi.org/10.1039/d6cc00167j

Anionic Inverse Vulcanization of 3-Methyleneazetidine for Reusable Adhesives | Synapse