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The wavelength shift with pressure of the ruby R1 fluorescence line (Δλ) has been calibrated in the diamond-window pressure cell from 0. 06 to 1 Mbar. This was done by simultaneously making specific volume measurements of four metals (Cu, Mo, Ag, and Pd) and referring these results to isothermal equations of state derived from shock-wave experiments. The result is P (Mbar) = (19. 04/5) (λ0+Δλ) /λ05−1, where λ0 is the wavelength measured at 1 bar.
Mao et al. (Thu,) studied this question.