April 26, 2008Organic Letters393 citations

Assisted Ruthenium-Catalyzed C−H Bond Activation: Carboxylic Acids as Cocatalysts for Generally Applicable Direct Arylations in Apolar Solvents

Lutz AckermannUniversidade Federal de Minas Gerais RVR. VicenteUniversidad de Oviedo AAAndreas AlthammerChinese Academy of Sciences

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Resumen

Catalytic amounts of aromatic carboxylic acid MesCO H enabled efficient ruthenium-catalyzed direct arylations in apolar solvents with unparalleled broad scope via a concerted deprotonation-metalation mechanism.

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Ackermann et al. (2008) studied this question.

synapsesocial.com/papers/6a87b5325a7984ab7cfb052d https://doi.org/https://doi.org/10.1021/ol800773x

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