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Abstract The large size of K + ions (1.38 Å) sets a challenge in achieving high kinetics and long lifespan of potassium storage devices. Here, a fibrous ZrO 2 membrane is utilized as a reactive template to construct a dual‐carbon K‐ion capacitor. Unlike graphite, ZrO 2 ‐catalyzed graphitic carbon presents a relatively disordered layer arrangement with an expanded interlayer spacing of 0.378 nm to accommodate K + insertion/extraction. Pyridine‐derived nitrogen sites can locally store K‐ions without disrupting the formation of stage‐1 graphite intercalation compounds (GICs). Consequently, N‐doped hollow graphitic carbon fiber achieves a K + ‐storage capacity (primarily below 1 V), which is 1.5 time that of commercial graphite. Potassium‐ion hybrid capacitors are assembled using the hollow carbon fiber electrodes and the ZrO 2 nanofiber membrane as the separator. The capacitor exhibits a high power of 40 000 W kg −1 , full charge in 8.5 s, 93% capacity retention after 5000 cycles at 2 A g −1 , and a low self‐discharge rate of 8.6 mV h −1 . The scalability and high performance of the lattice‐expanded tubular carbon electrodes underscores may advance the practical potassium‐ion capacitors.
Shi et al. (Sat,) studied this question.