SiC@NiO Core–Shell Nanowire Networks‐Based Optoelectronic Synapses for Neuromorphic Computing and Visual Systems at High Temperature

Abstract 1D nanowire networks, sharing similarities of structure, information transfer, and computation with biological neural networks, have emerged as a promising platform for neuromorphic systems. Based on brain‐like structures of 1D nanowire networks, neuromorphic synaptic devices can overcome the von Neumann bottleneck, achieving intelligent high‐efficient sensing and computing function with high information processing rates and low power consumption. Here, high‐temperature neuromorphic synaptic devices based on SiC@NiO core–shell nanowire networks optoelectronic memristors (NNOMs) are developed. Experimental results demonstrate that NNOMs attain synaptic short/long‐term plasticity and modulation plasticity under both electrical and optical stimulation, and exhibit advanced functions such as short/long‐term memory and “learning–forgetting–relearning” under optical stimulation at both room temperature and 200 °C. Based on the advanced functions under light stimulus, the constructed 5 × 3 optoelectronic synaptic array devices exhibit a stable visual memory function up to 200 °C, which can be utilized to develop artificial visual systems. Additionally, when exposed to multiple electronic or optical stimuli, the NNOMs effectively replicate the principles of Pavlovian classical conditioning, achieving visual heterologous synaptic functionality and refining neural networks. Overall, with abundant synaptic characteristics and high‐temperature thermal stability, these neuromorphic synaptic devices offer a promising route for advancing neuromorphic computing and visual systems.