What question did this study set out to answer?

The research aims to design and synthesize new chiral bisulidine ligands for use in asymmetric catalysis.

January 14, 2026

Crab-shape C2-symmetric chiral Tpy-bisulidine ligands: design, synthesis and application in diversity-oriented asymmetric catalysis

Key Points

The research aims to design and synthesize new chiral bisulidine ligands for use in asymmetric catalysis.
Utilized crab-shaped C2-symmetrical architecture for ligand design.
Synthetized chiral Tpy-bisulidine ligands through novel methods.
Tested ligands in diverse asymmetric catalysis reactions.
New ligands showed enhanced coordination with metal ions.
Achieved improved yields in asymmetric reactions compared to conventional ligands.

Abstract

Terpyridine-type ligands were renowned for their rich coordination with various metal ions. However, their high cost and tedious preparation methods limit their further application in asymmetric catalysis. Herein, we prepared...

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Authors

Li Wuwu

Hong-Xing Cen

Di-Cheng Pan

Journals

Organic Chemistry Frontiers

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Crab-shape C2-symmetric chiral Tpy-bisulidine ligands: design, synthesis and application in diversity-oriented asymmetric catalysis

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Abstract

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