Synthesis, structural characterization and properties of a series of heteropolyoxomolybdates: AlMo 6 (OH) 6 O 18 3− , GeMo 12 O 40 4− , GeMo 6 O 22 (Hmal) 3 7− , SiMo 12 O 40 4− , and TeMo 6 O 24 6−

Key Points

• This research aims to synthesize and characterize a series of heteropolyoxomolybdates and their structural properties.
• Synthesis of Anderson-type and Keggin-type compounds
• Isolation of coordination polymer with various cations
• Characterization of molecular structures
• Isolation of distinct heteropolyoxomolybdates with specific structural types
• Identification of reaction intermediates during synthesis
• Characterization suggests potential applications for these compounds