What does this research mean for the field?

Arene-Ru(II) complexes catalyze efficient ammonia borane dehydrogenation in water at 25 °C, achieving high turnover number (TON) and turnover frequency (TOF). Novelty: ClaimNovelty.NOVEL_FINDING. Consensus alignment: ConsensusAlignment.NEUTRAL.

What question did this study set out to answer?

To examine the efficiency of arene-Ru(II) complexes as catalysts in ammonia borane dehydrogenation in water.

February 21, 2026

Hydride-Mediated Ammonia Borane Dehydrogenation in Water by Arene-Ru(II) Catalysts Revealed through Real-Time Gas Evolution

Key Points

To examine the efficiency of arene-Ru(II) complexes as catalysts in ammonia borane dehydrogenation in water.
Kinetic analysis of the dehydrogenation reaction
Investigation of the effect of catalyst concentration
Measurement of gas evolution in real-time
Achieved high turnover number (TON) and turnover frequency (TOF) for ammonia borane dehydrogenation
Demonstrated pseudo-first-order kinetics concerning both Ru catalyst and ammonia borane
Confirmed effective catalytic performance at room temperature (25 °C)

Abstract

Arene-Ru(II) complexes catalyse efficient Ammonia Borane (AB) dehydrogenation in water at 25 °C, delivering high TON and TOF. Kinetic analysis reveals pseudo-first-order behaviour on both Ru and AB; a hydride-Ru...

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Hydride-Mediated Ammonia Borane Dehydrogenation in Water by Arene-Ru(II) Catalysts Revealed through Real-Time Gas Evolution

Key Points

Abstract

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