Crystal structure of polyμ 2 -aqua-bis(μ 3 -3-carboxylatomethylbenzoato-k 3 O:O:O ″)(μ 2 -di(pyridin-4-yl)sulfane-k 2 N:N ′)dimanganese(II), C 38 H 30 Mn 2 N 4 O 9 | Synapse
March 2, 2026Open Access
Crystal structure of polyμ 2 -aqua-bis(μ 3 -3-carboxylatomethylbenzoato-k 3 O:O:O ″)(μ 2 -di(pyridin-4-yl)sulfane-k 2 N:N ′)dimanganese(II), C 38 H 30 Mn 2 N 4 O 9
Key Points
The study aims to determine the crystal structure of a manganese complex involving specific ligands.
Conducted single crystal X-ray diffraction to achieve structural characterization
Utilized orthorhombic crystal system with specific lattice parameters
Analyzed unit cell dimensions and symmetry.
The complex was determined to be orthorhombic with a volume of 3662.0 ų
Identified key structural features, including bi- and tri-dentate coordination
Provided R factors indicating high-quality data (R gt (F) = 0.0428, wR ref (F²) = 0.0944).
Abstract
Abstract C 38 H 30 Mn 2 N 4 O 9 , orthorhombic, Pca 2 1 (no. 29), a = 12.6212(6) Å, b = 16.4853(7) Å, c = 17.6002(7) Å, V = 3662.0(3) Å 3 , Z = 4, R gt ( F ) = 0.0428 wR ref ( F 2 ) = 0.0944, T = 293.2(2) K.