Shale gas has received considerable attention as a clean and high-quality energy resource, while CO2 injection into shale reservoirs is increasingly explored for its potential to enhance CH4 recovery and reduce emissions. Shale exhibits a wide pore size distribution, with micropores (2 storage potential with emphasis on significance of both micropores and mesopores. First, the pore morphology and topology characterization using techniques such as electron microscopy, probe gas adsorption, and connectivity analysis were reviewed. Reservoir conditions, shale characteristics, and gas compositions of six typical shale reservoirs were summarized. Second, the gas states in shale nanopores, including free, adsorbed, and absorbed phases, were evaluated due to their importance in estimating GIP. The sorption isotherms for the six representative shale reservoirs, adsorption models, and excess-to-absolute conversion methods were summarized. Molecular simulation models were also reviewed and compared to elucidate adsorption mechanisms at the nano scale, highlighting kerogen models with both micropores and mesopores that better represent experimental adsorption behavior. Third, production mechanisms and CO2 storage potential were reviewed. Field tests, experiments, and molecular simulations on CO2 huff-n-puff were summarized. CO2 injection in shale can effectively enhance CH4 recovery and store CO2, due to its higher affinity compared to CH4. Formation-specific and global CO2 storage potential of shale were analyzed. Based on our previous molecular simulation and the assumption that technically recoverable CH4 can be replaced by CO2, we estimated the global shale CO2 storage capacity to exceed 570 Gt. This review provides methodological guidance for simulations and experiments and supports future efforts in shale energy development and CO2 sequestration.
Li et al. (Thu,) studied this question.