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Two-dimensional (2D) materials have been well developed for polarization-sensitive photodetection, while new 2D members used in shortwave region (>2.5 eV) still remain scarce. The family of 2D hybrid perovskite ferroelectrics, in which the coupling of spontaneous polarization (Ps) and light benefits dissociation of photoinduced carriers, has shown great potential in this portfolio. Here, we report a new 2D hybrid perovskite ferroelectric, CH3(CH2)3NH32(CH3NH3)Pb2Br7 (1), which exhibits a superior Ps of 3.6 μC/cm2 and a relatively wide bandgap (∼2.55 eV). The unique 2D perovskite motif results in an intrinsic anisotropy of optical absorption (the ratio αc/αa ≈ 1.9 at 405 nm), involving its polarization-sensitive activity. As expected, the strongest photoresponses were observed along the c-axis (i.e., parallel to Ps), along with a large dichroism ratio (Iphc/Ipha ≈ 2.0) and highly sensitive detectivity up to ∼109 Jones. Further, crystal-device of 1 shows a fast responding rate (∼20 μs) and excellent antifatigued merits. As pioneering work, 1 is the first polarization-sensitive ferroelectric in the new branch of 2D hybrid perovskites. Such intriguing behaviors make 1 a potential candidate for the shortwave polarized-light detection, which also sheds light on new functionalities for future optoelectronic application of hybrid perovskites.
Li et al. (Sun,) studied this question.