What question did this study set out to answer?

The research aims to understand how geometry affects charge separation and recombination in donor-acceptor systems.

April 10, 2026Open Access

Conformationally Locked BODIPY Donor–Acceptor Dyads: Charge Separation and Recombination across a 2.2.2Bicyclooctane Spacer

Key Points

The research aims to understand how geometry affects charge separation and recombination in donor-acceptor systems.
Investigation of excited-state dynamics in D-A dyads
Analysis of charge-separated states
Study of intramolecular rotations and vibrations
Identified challenges in controlling excited-state dynamics
Demonstrated effects of molecular geometry on charge dynamics
Clarified the role of conformational locking in charge behavior

Abstract

Controlling the excited-state dynamics of charge-separated (CS) states in donor-acceptor (D-A) systems is challenging due to geometry changes from intramolecular rotations and vibrations. A key question is how molecular geometry...

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Authors

Metodej Dvoracek

Technological University Dublin

Yanran Wu

Dalian University of Technology

Greta Sambucari

Nello Carrara Institute of Applied Physics

Journals

Journal of Materials Chemistry C

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Conformationally Locked BODIPY Donor–Acceptor Dyads: Charge Separation and Recombination across a 2.2.2Bicyclooctane Spacer

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Abstract

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