September 1, 2004

CuBr-Catalyzed Efficient Alkynylation of sp3 C−H Bonds Adjacent to a Nitrogen Atom

ZLZhiping LiChongqing University of Posts and Telecommunications CLChao‐Jun LiUniversity of Notre Dame

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Abstract

A simple and effective catalytic method to construct propargylamine was developed by using copper bromide and tert-BuOOH via a combination of sp3 C-H bond and sp C-H bond activations followed by C-C bond formation.

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Li et al. (Wed,) studied this question.

synapsesocial.com/papers/69dd5dcd4917c2595e101552 https://doi.org/https://doi.org/10.1021/ja0460763

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