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A Pd(II)-catalyzed C-H phosphorylation reaction has been developed using heterocycle-directed ortho-palladation. Both H-phosphonates and diaryl phosphine oxides are suitable coupling partners for this reaction.
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Chen‐Guo Feng
Shanghai University of Traditional Chinese Medicine
Mengchun Ye
Nankai University
Kai‐Jiong Xiao
Merck & Co., Inc., Rahway, NJ, USA (United States)
Journal of the American Chemical Society
Scripps Research Institute
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Feng et al. (Tue,) studied this question.
synapsesocial.com/papers/69dff7e72833447a7e255b2e — DOI: https://doi.org/10.1021/ja404526x