Boron as a key component for new π-electron materials

Abstract For the molecular design of new π-electron materials, the incorporation of main group elements into the π-conjugated frameworks is a powerful approach to modifying the nature of the parent π-conjugated systems. In particular, the group 13 boron is of interest, since the boron element has several characteristic features, such as an effective orbital interaction with the π-conjugated frameworks through the vacant p-orbital (i.e., p π -π* conjugation), high Lewis acidity, and trigonal planar geometry. By exploiting these features of the boron atom, we have designed and synthesized several types of new π-electron materials, including trianthrylborane- or dibenzoborole-based π-conjugated systems as a new fluoride ion sensor, boryl-substituted thienylthiazole as a new building unit for electron-transporting materials, and B , B ', B ''-trianthrylborazine (B 3 N 3 )-based materials as a model of the bundled system of π-conjugated frameworks.