Carbon nanotube yarn (CNTY) monofilament composites were investigated for integrated temperature sensing by embedding a single CNTY in a vinyl ester resin (VER) and measuring the electrical resistance change by tapping into the thermoresistive response of the CNTY. The effect of curing condition on the thermoresistive response was evaluated using dwell tests and repeated heating–cooling cycles, comparing specimens cured at room temperature (RT) with those post-cured at 140 °C for 1 h. RT-cured CNTY/VER monofilament composites exhibited electrical resistance drift, with the resistance failing to return to its initial value after each thermal cycle, resulting in a residual resistance change of ~8.85%. In contrast, post-cured (PC) specimens showed a much smaller residual change (−0.08%) after cycle completion. Thermal cycling from RT (~25 °C) to 100 °C produced a nearly linear negative thermoresistive response. The average heating and cooling TCR values were −7.98 × 10−4 °C−1 and −8.32 × 10−4 °C−1 for CNTY/VER, and −7.93 × 10−4 °C−1 and −7.13 × 10−4 °C−1 for CNTY/VER-PC, respectively. The hysteresis decreased from 21.65% for RT-cured specimens to 12.49% after post-curing, accompanied by improved linearity. The influence of heating rate on TCR was also examined for both freestanding CNTYs and CNTY/VER monofilament composites. The observed response is attributed to coupled matrix–yarn effects (wetting, resin infiltration, and shrinkage) together with temperature-dependent electron transport across CNT junctions. Finally, CNTY/VER monofilament composites demonstrated the ability to estimate internal temperatures under various thermal programs.
Alowaid et al. (Thu,) studied this question.