What does this research mean for the field?

Incorporating magnesium into a ZIF-8 framework creates a mixed-metal solid solution that reduces zinc toxicity and increases water stability under mildly acidic conditions due to reduced polarizability. Novelty: ClaimNovelty.INCREMENTAL. Consensus alignment: ConsensusAlignment.NEUTRAL.

April 28, 2026ACS Omega0 citationsOpen Access

An Mg Solid Solution Affords a Less Toxic and More Stable ZIF-8

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NNNicola di NicolaUniversity of L'Aquila ESEnrico SpolettiUniversity of Bern PCPierre CezadeUniversity of Bern

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Abstract

affords a mixed-metal ZIF-8 analogue with up to 20% of the alkali heart. Besides reducing the dose of zinc, the solid solution shows increased water stability under mildly acidic conditions. DFT calculations point to a reduction of the MOF's polarizability as a cause for the observed behavior. Ideally, the changes in the Zn/Mg ratio would correspond to a modulation of such stability; however, equal stability improvement was measured over a range of compositions.

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Nicola et al. (Tue,) studied this question.

synapsesocial.com/papers/6a1ffaf8224ca8e946ecaee8 https://doi.org/https://doi.org/10.1021/acsomega.5c13152

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