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We report a novel nonvolatile dual-layered electrolytic resistance memory composed of a conductive Cu ion activated layer and a thin insulator for the first time. An ON/OFF mechanism of this new type memory is postulated as follows: Cu ions pierce through the insulator layer by applied electric field, the ions form a Cu conductive bridge in the insulator layer, and this bridge dissolves back to the ion activated layer when the field is reversed. The 4 kbit memory array with 1T-1R cell structure was fabricated based on 180 nm CMOS process. Set/reset pulses were 5 ns, 110 muA and 1 ns, 125 muA, respectively. Those conditions provide large set/reset resistance ratio of over 2 orders of magnitude and satisfactory retention. Essential characteristics for high capacity memories including superb scalability down to 20 nmphi, sufficient endurance up to 10 7 cycles and preliminary data for 4-level memory are also presented. These characteristics promise the memory being the next generation high capacity nonvolatile memory even before the scaling limitation of flash memories is encountered.
Aratani et al. (Sat,) studied this question.
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