Hydrothermal synthesis and crystal structure of polytris (μ 2 - cis -1, 4–cyclohexanedicarboxylato) -κ 2 O: O ′ ] -bisμ 3 -1, 3, 5-tris[ (1 H -imidazol-1-yl) methylbenzene-κ 3 N, N ′, N ″ ]trizinc (II) trihydrate, C 60 H 72 N 12 O 15 Zn 3 | Synapse
February 19, 2026Open Access
Hydrothermal synthesis and crystal structure of polytris (μ 2 - cis -1, 4–cyclohexanedicarboxylato) -κ 2 O: O ′ ] -bisμ 3 -1, 3, 5-tris[ (1 H -imidazol-1-yl) methylbenzene-κ 3 N, N ′, N ″ ]trizinc (II) trihydrate, C 60 H 72 N 12 O 15 Zn 3
Key Points
The study aims to characterize the crystal structure of a tris-zinc complex synthesized using hydrothermal methods.
Synthesis of poly{tris(μ2-cis-1,4–cyclohexanedicarboxylato)-κ2O:O′]-bis[μ3-1,3,5-tris[(1H-imidazol-1-yl)methyl]benzene-κ3N,N′,N″]trizinc(II) in hydrothermal conditions.
X-ray diffraction analysis performed to determine crystal structure and parameters.
Characterization of the compound at a temperature of 293 K.
The compound crystallizes in a trigonal structure with R32 symmetry.
Unit cell dimensions were found to be a = 17.9308(7) Å and c = 36.533(2) Å.
Calculated volume of the crystal is 10172.2(10) Å3.
Abstract
Abstract C 60 H 72 N 12 O 15 Zn 3 , trigonal, R 32 (no. 155), a = 17.9308(7) Å, c = 36.533(2) Å, V = 10172.2(10) Å 3 , Z = 18, R gt ( F ) = 0.0533, w R ref ( F 2 ) = 0.1488, T = 293 K.