Revealing the significant role of band structure asymmetry on thermoelectric bipolar conduction

Bipolar conduction, which is widely observed in various materials, plays a deleterious role in the thermoelectric properties. Traditionally, the single-band model is often applied to understand the transport properties of thermoelectric materials. However, it ignores the contribution from minority carriers and is incapable of quantifying the bipolar conduction. Herein, a general and feasible approach for calculating all the temperature-dependent transport properties based on the two-band model has been developed. In addition to the reduced electron Fermi energy and reduced band-gap energy, band structure asymmetry has been identified to play a significant role in bipolar conduction. Importantly, the effect of band structure asymmetry on bipolar conduction has been highlighted by using the Mg₃Bi₂-ₗSbₗ alloy as a typical example. Our results demonstrate that the band structure asymmetry is of great significance to the materials' thermoelectric performance.