Synthesis of a Rhenium(VII) Trioxo Complex Supported by a Triphyrin Ligand: Oxygenation Chemistry and Deposition on Au(111)

Key Points

• The aim is to synthesize and characterize rhenium complexes supported by a new triphyrin ligand.
• Synthesis of a [14]triphyrin ligand (TriPEt)
• Characterization of rhenium(I) and rhenium(VII) complexes
• Investigation of self-assembled monolayers on Au(111) surfaces
• Successful synthesis of [Re(TriPEt)(CO)₃] and [ReO₃(TriPEt)] complexes
• Characterization of complexes in bulk and on gold surfaces
• Self-assembly observed on Au(111)