Synthesis of a Rhenium(VII) Trioxo Complex Supported by a Triphyrin Ligand: Oxygenation Chemistry and Deposition on Au(111)

Manh Linh Nguyen; Thomas Strunskus; Christian Näther; Jan Krahmer; Felix Tuczek

doi:10.1039/d6dt00370b

January 1, 2026Dalton TransactionsOpen Access

Synthesis of a Rhenium(VII) Trioxo Complex Supported by a Triphyrin Ligand: Oxygenation Chemistry and Deposition on Au(111)

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Key Points

The aim is to synthesize and characterize rhenium complexes supported by a new triphyrin ligand.
Synthesis of a [14]triphyrin ligand (TriPEt)
Characterization of rhenium(I) and rhenium(VII) complexes
Investigation of self-assembled monolayers on Au(111) surfaces
Successful synthesis of [Re(TriPEt)(CO)₃] and [ReO₃(TriPEt)] complexes
Characterization of complexes in bulk and on gold surfaces
Self-assembly observed on Au(111)

Implication

New triphyrin ligand facilitates synthesis of rhenium complexes on gold surfaces, suggesting advances in material chemistry.

Abstract

A new [14]triphyrin(2.1.1) ligand (TriPEt, 1) is synthesized, and its rhenium(I) and rhenium(VII) complexes [Re(TriPEt)(CO)₃] (2) and [ReO₃(TriPEt)] (3) are characterized in the bulk and on Au(111) surfaces. Self-assembled monolayers...

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Cite This Study

Nguyen et al. (2026) studied this question.

synapsesocial.com/papers/69e3209340886becb653fb29 https://doi.org/10.1039/d6dt00370b

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Synthesis of a Rhenium(VII) Trioxo Complex Supported by a Triphyrin Ligand: Oxygenation Chemistry and Deposition on Au(111)

Key Points

Implication

Abstract

Discussion

Cite This Study

Synthesis of a Rhenium(VII) Trioxo Complex Supported by a Triphyrin Ligand: Oxygenation Chemistry and Deposition on Au(111)

Key Points

Implication

Abstract

Discussion

Cite This Study

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