Synthesis and Characterization of Stable Nickel(II) Complexes Bearing Long Alkyl Chains

Yuya Miyake; Koichiro Masada; Kyoko Nozaki

doi:10.1039/d5fd00083a

January 1, 2025Faraday Discussions

Synthesis and Characterization of Stable Nickel(II) Complexes Bearing Long Alkyl Chains

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Key Points

Stable nickel(II) complexes were produced successfully through ethylene oligomerization, showcasing a novel synthesis method.
The complex formation involved an anionic bidentate (P–O) ligand, critical for achieving stability in the resulting solids.
Synthesis was characterized in terms of the interaction of long alkyl chains with nickel(II), enhancing stability and solubility properties.
Findings call for further exploration of nickel(II) complexes in applications where stable solid-state forms are essential.

Implication

Synthesis of stable nickel(II) complexes using ethylene oligomerization, indicating the role of alkyl chains.

Abstract

Nickel(II) complexes bearing long alkyl chains are successfully obtained as stable solids by ethylene oligomerization usnig a SHOP type anionic bidentate (P–O) ligand. In contrast to the salient stability of...

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Cite This Study

Miyake et al. (2025) studied this question.

synapsesocial.com/papers/68a360e00a429f797332923f https://doi.org/10.1039/d5fd00083a

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Synthesis and Characterization of Stable Nickel(II) Complexes Bearing Long Alkyl Chains

Key Points

Implication

Abstract

Discussion

Cite This Study

Synthesis and Characterization of Stable Nickel(II) Complexes Bearing Long Alkyl Chains

Key Points

Implication

Abstract

Discussion

Cite This Study

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