This analysis reveals that a thorium(ii) hydride synthon promotes four-electron reductive coupling, suggesting broader applications for bimetallic complexes.
The double-sandwich bimetallic hydride complex [(Cp Ar5 )Th(μ-H)] 2 , regarded as a thorium( ii ) hydride synthon, not only serves as the six-electron transfer reagent, but also promotes the four-electron reductive coupling and Th–H addition reactions.
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Shi et al. (2025) studied this question.
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