A unified theory of pore-scale chaotic advection

Recent studies reveal the central role of chaotic advection in controlling pore-scale processes including solute mixing and dispersion, chemical reactions, and biological activity. These dynamics have been observed in porous media (PM) with a continuous solid phase (such as porous networks) and PM comprising discrete elements (such as granular matter). However, a unified theory of chaotic advection across these continuous and discrete classes of PM is lacking. Key outstanding questions include: (i) topological unification of discrete and continuous PM; (ii) the impact of the non-smooth geometry of discrete PM; (iii) how exponential stretching arises at contact points in discrete PM; (iv) how fluid folding arises in continuous PM; (v) the impact of discontinuous mixing in continuous PM; and (vi) generalised models for the Lyapunov exponent in both PM classes. We address these questions via a unified theory of pore-scale chaotic advection. We show that fluid stretching and folding (SF) in discrete and continuous PM arise via the topological complexity of the medium. Mixing in continuous PM manifests as discontinuous mixing through a combination of SF and cutting and shuffling (CS) actions, but the rate of mixing is governed by SF only. Conversely, discrete PM involves SF motions only. These mechanisms are unified by showing that continuous PM is analogous to discrete PM with smooth, finite contacts. This unified theory provides insights into the pore-scale chaotic advection across a broad class of porous materials and points to design of novel porous architectures with tuneable mixing and transport properties.