Magnetic superexchange couplings in doubly bis(2-pyridyl)pyrazolato-bridged dinuclear copper(II) complexes

Michio KAWANO; Yingying Wu; Zhao‐Yang Li; Akio Mishima; Satoshi Kawata; Ryuta Ishikawa

doi:10.1039/d5nj02006a

January 1, 2025New Journal of ChemistryOpen Access

Magnetic superexchange couplings in doubly bis(2-pyridyl)pyrazolato-bridged dinuclear copper(II) complexes

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Key Points

Magnetic superexchange couplings enhance interactions in synthesized copper(II) complexes, indicating analytical potential.
The dinuclear copper(II) complex showed unique properties, derived from CuCl2 and pyrazole in a specific solvent.
Single-crystal X-ray diffraction provided detailed structural insights into the copper(II) complex's formation.
Results indicate that these complexes could be valuable for studying magnetic behaviors and applications.

Implication

Solvothermal reaction yielded dinuclear copper(II) complex, highlighting magnetic superexchange properties.

Abstract

The solvothermal reaction of CuCl 2 ·2H 2 O with 3,5-bis(2-pyridyl)pyrazole (Hbpypz) in a methanol/water mixed solvent produces a dinuclear Cu II complex, formulated as syn -[Cu 2 (μ-bpypz) 2 Cl 1.5 (H 2 O) 0.5 ]Cl 0.5 ·3H 2 O. Single-crystal X-ray diffraction analysis revealed that the two Cu II ...

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KAWANO et al. (2025) studied this question.

synapsesocial.com/papers/68af432fad7bf08b1ead2512 https://doi.org/10.1039/d5nj02006a

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Magnetic superexchange couplings in doubly bis(2-pyridyl)pyrazolato-bridged dinuclear copper(II) complexes

Key Points

Implication

Abstract

Discussion

Cite This Study

Magnetic superexchange couplings in doubly bis(2-pyridyl)pyrazolato-bridged dinuclear copper(II) complexes

Key Points

Implication

Abstract

Discussion

Cite This Study

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