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August 22, 2025Angewandte Chemie0 citations

Molecular Insights into Active Sites of Manganese Oxide Water Oxidation Electrocatalysts

Molecular Insights into Active Sites of Manganese Oxide Based Water Oxidation Eletrocatalysts

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Authors

TWTongshuai WangCYChao YangHXH. Xiao

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Overview

Electrochemical analysis reveals high Faradic efficiency for a tri-manganese complex in water oxidation, implying design potential for manganese electrocatalysts.

Key Points

  • The defective cubical tri-manganese complex exhibits a Faradic efficiency of 95% for oxygen production, demonstrating its effectiveness as a molecular catalyst.
  • Electrochemical results show an average oxygen generation rate of 46.4 µmol h cm−2, indicating superior performance among manganese-based molecular catalysts.
  • Comparison with heterogeneous manganese oxides highlights the tri-manganese complex's potential in optimizing water oxidation catalysts.
  • Insights into the active centers of manganese oxides may influence future designs of efficient electrocatalysts for water oxidation.

Cite This Study

Wang et al. (2025) studied this question.

synapsesocial.com/papers/68af541fad7bf08b1eadb9a8https://doi.org/10.1002/ange.202511664
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