Latent asymmetry of gate opening and closing in a flexible MOF probed by time-resolved in-situ XRD

Shotaro Hiraide; Hideki Tanaka; Shogo Kawaguchi; Satoshi Watanabe

doi:10.1039/d5cc04347f

January 1, 2025Chemical Communications

Latent asymmetry of gate opening and closing in a flexible MOF probed by time-resolved in-situ XRD

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Key Points

Gate closing pathways for CO2 and n-butane exhibit significant asymmetry, demonstrating differentiating characteristics in flexible MOFs.
Time-resolved in-situ X-ray diffraction indicates clear distinctions in emission of gate transitions between gases, underscoring practical applications.
Analysis utilizing advanced diffraction techniques showcases the unique shifting mechanisms in metal-organic frameworks like ELM-11 over time.
Findings suggest potential enhancements in gas separation technologies through a deeper understanding of gate dynamics in flexible MOFs.

Implication

Time-resolved analysis reveals asymmetric gate transitions in the flexible metal-organic framework ELM-11, suggesting implications for gas separation processes.

Abstract

Time-resolved in-situ X-ray diffraction reveals a latent asymmetry in the gate-type transitions of the flexible metal-organic framework ELM-11. The gate-closing pathways for CO 2 and n -butane are highly asymmetric and distinct...

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Cite This Study

Hiraide et al. (2025) studied this question.

synapsesocial.com/papers/68af55c6ad7bf08b1eadbc54 https://doi.org/10.1039/d5cc04347f

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Latent asymmetry of gate opening and closing in a flexible MOF probed by time-resolved in-situ XRD

Key Points

Implication

Abstract

Discussion

Cite This Study

Latent asymmetry of gate opening and closing in a flexible MOF probed by time-resolved in-situ XRD

Key Points

Implication

Abstract

Discussion

Cite This Study

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