Gold-catalyzed cycloisomerizations produce distinct polycyclic structures, suggesting temperature impacts selectivity.
Divergent gold-catalyzed cycloisomerizations of o -cyclopropylidenemethyl- o ′-alkynylbiaryls give access to two distinct polycyclic scaffolds containing a tricyclic bridgehead carbon center, with selectivity controlled by temperature.
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Sánchez et al. (2025) studied this question.
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