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August 27, 2025Synfacts

Enantioselective Minisci-Type Addition to Heteroarenes Using Mesoporous g-C3N4 under Red-Light Irradiation

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Key Points

Enantioselectivity improves the yield of fused chiral compounds significantly during reactions under specific light conditions.
Analysis shows increased reaction rates by approximately 30% when using graphitic carbon nitride as a photocatalyst.
Laboratory experiments utilized red-light irradiation to facilitate the Minisci-type addition process with distinct heteroarenes.
Findings point towards the potential of chiral phosphoric acids to optimize photocatalytic synthesis in future applications.

Implication

Minisci-type addition enhances asymmetric reaction efficiency in heteroarenes, suggesting new photocatalytic applications.

Abstract

Keywords photocatalysis - Minisci-type addition - asymmetric reaction - graphitic carbon nitride - chiral phosphoric acids - heteroarenes

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Cite This Study

A 2025 study studied this question.

synapsesocial.com/papers/68b033590a36ac2c8db3ccb9 https://doi.org/10.1055/a-2653-4548

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Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Catalytic enantioselective Minisci-type addition to heteroarenesOriginal Research · 2018 · 534 citations
2Photocatalyst‐Free Chiral Phosphoric Acid‐Catalyzed Enantioselective Minisci‐Type Alkylation of N‐Heteroarenes2024 · 4 citations
3Diazaphospholene Hydrides Catalyze Enantioselective Reductive Eschenmoser–Claisen Rearrangements2024
4Enantioselective [2+2] Cross-Photocycloaddition Using a Homochiral Metal–Organic Cage Reactor2024
5Visible-Light-Mediated Three-Component Minisci-Type Reaction of 4-Cyanopyridines.2025 · 3 citations

More related papers

Enantioselective Reactions of Redox-Active Esters Catalyzed via Cooperative Photoredox/Chiral Phosphoric Acid Catalysis2025
Photoredox-mediated Minisci C–H alkylation of N-heteroarenes using boronic acids and hypervalent iodine2016
Heterogeneous g‐C <sub>3</sub> N <sub>4</sub> Photocatalyzed Platform for Diverse CH Functionalization of Heteroarenes With Hydrazines2026

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