Ni-mediated cross coupling leads to aryl C-glycosides from glycosyl sulfinates, suggesting efficiency in synthesis.
Unprotected glycosyl sulfinates undergo Ni-mediated cross coupling with a range of aryl iodides and bromides under photoredox conditions to yield aryl C-glycosides, predominantly as the β-anomers. Thioglycoside formation is occasionally...
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Talukdar et al. (2025) studied this question.
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