Observational analysis shows distinct catalytic roles of iron dihydride and iron borohydride in hydrogenation of alkenes, highlighting their different effectiveness.
An iron dihydrido complex [(Me 4 PNP iPr )Fe(H) 2 (N 2 )] with a bulky tetramethylated PNP pincer ligand, Me 4 PNP iPr , is an active catalyst for full hydrogenation of internal alkynes and alkenes, while its reactivity with terminal...
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Pandey et al. (2025) studied this question.
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