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Calculations reveal ionization cross sections for acenes naphthalene through hexacene, suggesting similar energy peaks.
We present calculations of the ionization cross sections for collisions of electrons and positrons with the acene molecules naphthalene, anthracene, tetracene, pentacene, and hexacene. The computations are performed using the binary-encounter Bethe (BEB) model and its modifications for positrons. The results show that all acenes exhibit maxima in their ionization cross sections at the same incident energy, regardless of molecular size. Furthermore, we find that the magnitude of the cross sections scales linearly with the number of rings in the acene molecules.
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Baksalary et al. (2025) studied this question.
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