This research demonstrates the synthesis of polymorphic copper iodide clusters using a solvent-mediated approach, indicating improved phosphorescent properties.
Based on crystalline polymorphism, we utilized a solvent-mediated crystal engineering strategy to synthesize three polymorphic copper-iodide clusters, 1 [Cu4I4(4-dpda)4], 1-Tol [Cu4I4(4-dpda)4·C7H8], and 1-PX [Cu4I4(4-dpda)4·C8H10] (4-dpda = 4-(diphenylphosphino)-N,N-dimethylaniline), respectively. The polymorphic...
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Huang et al. (2025) studied this question.
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