Pincer Chromium (II) Catalyzed Hydrogenation of CO2, and Bicarbonate to Formate

Tushar Singh; Subrata Chakraborty

doi:10.1039/d5dt00070j

January 1, 2025Dalton Transactions

Pincer Chromium (II) Catalyzed Hydrogenation of CO2, and Bicarbonate to Formate

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Key Points

The reaction produces formate through catalytic hydrogenation of carbon dioxide, showcasing its effectiveness.
The Cr(II) pincer complex was utilized with NaHBEt3, indicating a precise catalytic mechanism for this process.
Experimental results led to the discovery of a new pathway for formate production from CO2, expanding potential applications.
This catalytic approach provides a promising strategy for CO2 conversion in sustainable chemistry.

Implication

This research demonstrates catalytic hydrogenation of carbon dioxide to formate with chromium, indicating a novel approach in carbon capture.

Abstract

Presenting here is catalytic hydrogenation of carbon dioxide to formate using a Cr(II) pincer complex. The complex CrCl2(PNP) C-1 {PNP = N,N-bis(diphenylphosphinoethyl)amine} in combination with NaHBEt3 in the presence of...

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Cite This Study

Singh et al. (2025) studied this question.

synapsesocial.com/papers/68c18f469b7b07f3a061618f https://doi.org/10.1039/d5dt00070j

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Pincer Chromium (II) Catalyzed Hydrogenation of CO2, and Bicarbonate to Formate

Key Points

Implication

Abstract

Discussion

Cite This Study

Pincer Chromium (II) Catalyzed Hydrogenation of CO2, and Bicarbonate to Formate

Key Points

Implication

Abstract

Discussion

Cite This Study

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