Melem‐Perylene Diimide Polymer Network as Efficient Positive Electrode for Rechargeable Lithium and Magnesium Batteries

Organic battery electrode materials represent a sustainable alternative compared to most inorganic electrodes, yet challenges persist regarding their energy density and cycling stability. In this work, a new organic electrode material is described, which is obtained via ionothermal polymerization of low‐cost starting materials, melem (2,5,8‐triamino‐tri‐ s ‐triazine) and perylenetetracarboxylic dianhydride (PTCDA). The resulting networked polymer Melem‐PDI exhibits favorable thermal and electrochemical properties, prompting investigation into its performance as a positive electrode material in rechargeable lithium and magnesium batteries. A hybrid material with carbon nanotubes ( Melem‐PDI‐CNT ) is found to exhibit‐excellent cycling stability in Li‐ion batteries at a current rate as high as 500 mA g −1 for 5000 cycles. While the Li‐ion storage is based on a pseudocapacitive mechanism, a diffusion‐controlled mechanism is observed in magnesium batteries. This work underscores that classic dyes (here: PDI) can be repurposed for energy storage, once they are integrated into suitable polymer topologies and brought into nanoscale contact with conductive materials.