This research demonstrates enhanced H2O2 production using a Schiff base polymer electrocatalyst, suggesting innovative pathways for efficient catalysis.
The production of H2O2 via the two-electron pathway of ORR has been widely studied. We pioneered the use of a Zn-Schiff base conductive polymer nanorod as an electrocatalyst for H2O2 production, leveraging the Schiff base's ability to enhance electron transfer and catalytic efficiency. This novel catalyst achieved an unprecedented >98% H2O2 selectivity with >90% stability after 1000 h. In situ DRIFTS, in situ SERS, and theoretical calculations confirm the Schiff base's critical role in optimizing electron transfer for superior H2O2 generation.
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Sun et al. (2025) studied this question.
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