Isomer selection of heteroleptic Pd 2 L A 2 L B 2 coordination cages was achieved through precise tuning of interactions.
The study demonstrates that coordination sphere interactions are critical in determining isomer formation in Pd cages.
Tuning the interaction parameters resulted in selective assembly of coordination cages with low-symmetry ligands.
Understanding these interactions may lead to enhanced design of coordination complexes in materials science.
Resumen
The isomer selective formation of heteroleptic Pd 2 L A 2 L B 2 -type coordination cages assembled from low-symmetry ligands was demonstrated through tuning of coordination sphere interactions.